Macromolecular engineering by atom transfer radical polymerization.
Identifieur interne : 002325 ( Main/Exploration ); précédent : 002324; suivant : 002326Macromolecular engineering by atom transfer radical polymerization.
Auteurs : Krzysztof Matyjaszewski [États-Unis] ; Nicolay V. TsarevskySource :
- Journal of the American Chemical Society [ 1520-5126 ] ; 2014.
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Abstract
This Perspective presents recent advances in macromolecular engineering enabled by ATRP. They include the fundamental mechanistic and synthetic features of ATRP with emphasis on various catalytic/initiation systems that use parts-per-million concentrations of Cu catalysts and can be run in environmentally friendly media, e.g., water. The roles of the major components of ATRP--monomers, initiators, catalysts, and various additives--are explained, and their reactivity and structure are correlated. The effects of media and external stimuli on polymerization rates and control are presented. Some examples of precisely controlled elements of macromolecular architecture, such as chain uniformity, composition, topology, and functionality, are discussed. Syntheses of polymers with complex architecture, various hybrids, and bioconjugates are illustrated. Examples of current and forthcoming applications of ATRP are covered. Future challenges and perspectives for macromolecular engineering by ATRP are discussed.
DOI: 10.1021/ja408069v
PubMed: 24758377
Affiliations:
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Tsarevsky</name></author></analytic><series><title level="j">Journal of the American Chemical Society</title><idno type="eISSN">1520-5126</idno><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Catalysis</term><term>Kinetics</term><term>Polymerization</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Catalyse</term><term>Cinétique</term><term>Polymérisation</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Catalysis</term><term>Kinetics</term><term>Polymerization</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Catalyse</term><term>Cinétique</term><term>Polymérisation</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">This Perspective presents recent advances in macromolecular engineering enabled by ATRP. 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